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707171 Sigma-Aldrich

(1R,4R)-2,5-Diphenylbicyclo[2.2.2]octa-2,5-diene

95%

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Diene Ligands
assay   95%
optical activity   [α]22/D −34.0°, c = 0.5 in chloroform
mp   71-77 °C
storage temp.   −20°C
SMILES string   C1C[C@@H]2C=C([C@H]1C=C2c3ccccc3)c4ccccc4
InChI   1S/C20H18/c1-3-7-15(8-4-1)19-13-18-12-11-17(19)14-20(18)16-9-5-2-6-10-16/h1-10,13-14,17-18H,11-12H2/t17-,18-/m1/s1
InChI key   BDYBOFJAEBJDMI-QZTJIDSGSA-N
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Documents

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Protocols & Articles

Articles

Chiral Diene Ligands for Asymmetric Transformations

In the last few years, a number of chiral diene ligands have emerged for a variety of asymmetric transformations.1 This powerful new method has proven to be an efficient way for the construction of e...

ChemFiles 2010, 10.2, 4.


Keywords: Addition reactions, Asymmetric catalysis, Asymmetric synthesis, Building blocks, Catalysis, Cross couplings, Hydrosilylations, Ligands, Oxidations, Swern Oxidation

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