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707430 Sigma-Aldrich

2′-Dicyclohexylphosphino-2,4,6-trimethoxybiphenyl

97%

Synonym: Dicyclohexyl(2′,4′,6′-trimethoxy[1,1′-biphenyl]-2-yl)-phosphine

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Properties

Related Categories Buchwald Ligands, Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis,
assay   97%
mp   148-158 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Cross Couplings
SMILES string   COc1cc(OC)c(c(OC)c1)-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI   1S/C27H37O3P/c1-28-20-18-24(29-2)27(25(19-20)30-3)23-16-10-11-17-26(23)31(21-12-6-4-7-13-21)22-14-8-5-9-15-22/h10-11,16-19,21-22H,4-9,12-15H2,1-3H3
InChI key   NTHFAYYJLKWDAE-UHFFFAOYSA-N

Description

Application

Catalyst for Suzuki-Miyaura cross-coupling of Ph tosylates with potassium (phenyl)trifuoroborates

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

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