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708356 Sigma-Aldrich

2-Amino-4-bromophenol

≥94%

Synonym: 4-Bromo-2-aminophenol, NSC 523846

  • CAS Number 40925-68-6

  • Empirical Formula (Hill Notation) C6H6BrNO

  • Molecular Weight 188.02

  •  Beilstein/REAXYS Number 3236448

  •  MDL number MFCD00235171

  •  PubChem Substance ID 329762789

  •  NACRES NA.22

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Properties

Related Categories Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds - Organic Building Blocks,
Quality Level   100
assay   ≥94%
mp   130-135 °C
storage temp.   2-8°C
SMILES string   Nc1cc(Br)ccc1O
InChI   1S/C6H6BrNO/c7-4-1-2-6(9)5(8)3-4/h1-3,9H,8H2
InChI key   JHRIPENGTGSNPJ-UHFFFAOYSA-N

Description

Application

Reactant for:
• Preparation of (aryl)oxadiazolobenzoxazinones via Suzuki-Miyaura reaction
• Copper-catalyzed oxidative amination of benzoxazoles and related azoles via C-H and C-N bond activation
• Synthesis of N-(alkoxyphenyl)-aminocarbonylbenzoic acid derivatives as protein tyrosine phophatase 1B inhibitors
• Preparation of lipophilic deoxy-xylulose-phosphate reductoisomerase inhibitors
• Synthesis of benzoxazole benzenesulfonamides as allosteric inhibitors of fructose-1,6-bisphosphatase

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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