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  • 708763 - [(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

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708763 Sigma-Aldrich

[(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride

Synonym: [PdCl2{(S)-4-tolylbinap}]

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Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
mp   >300 °C
SMILES string   Cl[Pd]Cl.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
InChI   1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2
InChI key   ADMKISPNGKUJAU-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
• Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

Packaging

100, 500 mg in amber glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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