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711314 Sigma-Aldrich

Methyl(triphenylphosphine)gold(I)

98%

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
Quality Level   100
assay   98%
reaction suitability   core: gold
  reagent type: catalyst
mp   158 °C (dec.)
storage temp.   2-8°C
SMILES string   C[Au].c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI   1S/C18H15P.CH3.Au/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;1H3;
InChI key   GTYPEKWTQNTEKM-UHFFFAOYSA-N

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Packaging

500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Intermolecular Hydroamination

In 2003, Mizushima et al. reported the first intermolecular hydroamination of alkynes with primary amines.6 This new procedure, using gold as catalyst, allowed access to ketimides using relatively mi...
William Sommer
Aldrich ChemFiles 2009, 9.5, 3.
Keywords: Aminomercuration, Chemfiles, Hydroaminations

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