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715255 Sigma-Aldrich

trans-Bis(dicyclohexylamine)palladium(II) acetate

Synonym: DAPCy

  • CAS Number 628339-96-8

  • Empirical Formula (Hill Notation) C28H52N2O4Pd

  • Molecular Weight 587.14

  •  PubChem Substance ID 329762957

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
mp   150-154 °C
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string   CC(=O)O[Pd]OC(C)=O.C1CCC(CC1)NC2CCCCC2.C3CCC(CC3)NC4CCCCC4
InChI   1S/2C12H23N.2C2H4O2.Pd/c2*1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;2*1-2(3)4;/h2*11-13H,1-10H2;2*1H3,(H,3,4);/q;;;;+2/p-2
InChI key   GTVYHNQGNLJVAK-UHFFFAOYSA-L

Description

Application

Catalyst for:
• Coupling of aryl iodides with triarylbismuths
• Synthesis of 3,6-diphenyl-9-hexyl-9H-carazole derivatives
• Suzuki coupling of dihexylfluorene derivatives
• Suzuki-Miyaura coupling of dibromopyrone with boronic acids

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
1
Protocols & Articles
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