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716715 Sigma-Aldrich

(S)-2-[(Diphenylphosphino)methyl]pyrrolidine

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
InChI Key   IWRBGJKCDORZHK-HNNXBMFYSA-N
optical activity   [α]22/D −24.0°, c = 0.5 in ethanol
refractive index   n20/D 1.614
density   1.043 g/mL at 25 °C

Description

Application

Catalytic ligand in:
• Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
• Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal

Packaging

250 mg in amber glass bottle

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C

Documents

Certificate of Analysis

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Protocols & Articles
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