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717282 Sigma-Aldrich

Chloro[tri(p-tolyl)phosphine]gold(I)

97%

Synonym: Chloro[tri(4-methylphenyl)phosphine]gold(I)

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
assay   97%
reaction suitability   core: gold
  reagent type: catalyst
mp   205-210 °C
SMILES string   Cl[Au].Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3
InChI   1S/C21H21P.Au.ClH/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21;;/h4-15H,1-3H3;;1H/q;+1;/p-1
InChI key   QHHGSPBDJCGVPV-UHFFFAOYSA-M

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Reactant fro synthesis of:
• Phosphine-gold(I) derivatives
• Stable organogold(I) compound - catalyst for cyclization
• Gold(I) acetylide complexes
• Heterometallic gold(I)-rhenium(I) alkynyl complexes

Involved in reactions with unsaturated dimolybdenum anions

Reactant for oxidative addition of iodine to gold(I) complexes

Packaging

500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
1

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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