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717398 Sigma-Aldrich

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

Synonym: (Sp)-1-(Diphenylphosphino)-2-[(4S)-4-isopropyl-2-oxazolyl]ferrocene

  • CAS Number 163169-29-7

  • Empirical Formula (Hill Notation) C28H28FeNOP

  • Molecular Weight 481.35

  •  MDL number MFCD15144869

  •  PubChem Substance ID 329763485

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
Quality Level   100
assay   97%
optical activity   [α]20/D 366°, c = 0.1 in chloroform
mp   158-162 °C
SMILES string   [Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5
InChI   1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1
InChI key   FELCHLOAEMNOQM-GHVWMZMZSA-N

Description

Application

(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.

Packaging

100 mg in clear glass bottle

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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