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717479 Sigma-Aldrich

Dichloro[(±)−BINAP]digold(I)

97%

Synonym: Dichloro(2,2′-bis(diphenylphosphino)-1,1′-binaphthalene)digold(I)

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
assay   97%
reaction suitability   core: gold
  reagent type: catalyst
mp   335-350 °C
SMILES string   Cl[Au].Cl[Au].P(C1=CC=CC=C1)(C2=C(C3=C(C=CC4=C3C=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6)C7=C(C=CC=C7)C=C2)C8=CC=CC=C8
InChI   1S/C44H32P2.2Au.2ClH/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;;/h1-32H;;;2*1H/q;2*+1;;/p-2
InChI key   ALCLMPWXOJPBJG-UHFFFAOYSA-L

Description

Application

Gold Catalysts — 21st Century ′Gold Rush′

Catalyst for selective diboration of alkenes via base-assisted heterolytic cleavage

Packaging

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
2

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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