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  • 717754 - 1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate

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717754 Sigma-Aldrich

1,1′-Bis((2R,5R)-2,5-diisopropylphospholano)ferrocene(cyclooctadiene)rhodium(I) tetrafluoroborate

97%

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes More...
assay   97%
optical activity   [α]20/D 332°, c = 0.1 in methylene chloride
mp   235-238 °C
SMILES string   [Fe].[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC(C)[C@H]2CC[C@H](C(C)C)P2[C]3[CH][CH][CH][CH]3.CC(C)[C@H]4CC[C@H](C(C)C)P4[C]5[CH][CH][CH][CH]5
InChI   1S/2C15H24P.C8H12.BF4.Fe.Rh/c2*1-11(2)14-9-10-15(12(3)4)16(14)13-7-5-6-8-13;1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*5-8,11-12,14-15H,9-10H2,1-4H3;1-2,7-8H,3-6H2;;;/q;;;-1;;+1/b;;2-1-,8-7-;;;/t2*14-,15-;;;;/m11..../s1
InChI key   CEECLGREXPXHOQ-VXMPMTHESA-N

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Packaging

100 mg in clear glass bottle

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
nwg

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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