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719013 Sigma-Aldrich

(Piperidinium-1-ylmethyl)trifluoroborate

internal salt

  • CAS Number 1268340-93-7

  • Empirical Formula (Hill Notation) C6H13BF3N

  • Molecular Weight 166.98

  •  MDL number MFCD18071160

  •  PubChem Substance ID 329763622

  •  NACRES NA.22

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Properties

Related Categories Alkyl Trifluoroborate Salts, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trifluoroborate Salts More...
Quality Level   100
mp   134-149 °C
SMILES string   F[B-](F)(F)C[NH+]1CCCCC1
InChI   1S/C6H12BF3N/c8-7(9,10)6-11-4-2-1-3-5-11/h1-6H2/q-1/p+1
InChI key   PFMNVTAJBBIDDU-UHFFFAOYSA-O

Description

Application

(Piperidinium-1-ylmethyl)trifluoroborate can be used as a reagent in the palladium-catalyzed Suzuki-cross coupling reaction with aryl and heteroaryl halides/mesylates to prepare methylpiperidinyl derivatives.

Organotrifluoroborate involved in Suzuki-Miyaura cross-coupling and cross coupling with mesylated phenol derivatives

Organotrifluoroborates as versatile and stable boronic acid surrogates.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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