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  • 723673 - (1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene

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723673 Sigma-Aldrich

(1R,4R,7R)-7-Isopropyl-2-(1-hydroxy-1-methylethyl)-5-methylbicyclo[2.2.2]octa-2,5-diene

Synonym: (1R,4R,7R)-α,α,5-Trimethyl-7-(1-methylethyl)bicyclo[2.2.2]octa-2,5-diene-2-methanol

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Conjugate Addition
InChI Key   NDYITPSGAZLHSH-UPJWGTAASA-N
optical activity   [α]22/D +42.0°, c = 0.5 in chloroform
refractive index   n20/D 1.495
density   0.952 g/mL at 25 °C

Description

Packaging

1 g in glass bottle

Application

Reactant for:
• Chiral ligand for asymmetric 1,4-conjugate addition

Used for:
• Rh-catalyzed asymmetric conjugate addition reaction of boronic acids to α,β-unsaturated ketones
• Rhodium-catalyzed asymmetric arylation of imines

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
2
Protocols & Articles
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