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  • 730459 - (2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

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730459 Aldrich

(2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Green Alternative

Synonym: Fe(S,S-PDP), Iron(II) (S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White Catalyst, [Fe(S,S-PDP)(CH3CN)2](SbF6)2

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Properties

Related Categories 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts,
InChI Key   XUNWHBGEOCZDBX-QSKJABRXSA-B
optical activity   [α]20/D −30.0 to −20.0°, c = 0.2 in acetonitrile
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   >300 °C

Description

Packaging

100, 500 mg in glass bottle

Application

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Catalyst for:
• Oxidative radical reactions
• Selective oxidation of alkyl carbon-hydrogen bonds
• Methylene group oxidation

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport

Screeing simplified
Protocols & Articles

Articles

Chiral 2,2’-Bipyrrolidines

C2-symmetrical, chiral 2,2’-bipyrrolidines have recently emerged as interesting structural chiral motifs in a number of ligands for asymmetric transformations (Figure 1). When the two nitrogen atoms ...
Daniel Weibel
ChemFiles Volume 10 Article 4
Keywords: Asymmetric synthesis, Catalysis, Dihydroxylations, Ligands, Oxidations, Preferential Oxidation, Type

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