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734586 Sigma-Aldrich

2-(2-Bromoisobutyryloxy)ethyl methacrylate

95%

Synonym: 2-Methacryloxyethyl 2′-bromoisobutyrate, 2-Methylacrylic acid 2-(2-bromo-2-methylpropionyloxy) ethyl ester, BIEM

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Properties

Related Categories ATRP, ATRP Initiators, Acrylic Monomers, Materials Science, Methacrylate,
InChI Key   QXDYJUSFCUKOQD-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.471
density   1.303 g/mL at 25 °C
storage temp.   2-8°C

Description

Application

Atom Transfer Radical Polymerization (ATRP) initiator with a methacrylate functionality for branched polymerization, orthogonal polymerization, or other functionalization.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>230 °F
Flash Point(C) 
>110 °C
Protocols & Articles

Articles

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

In 2006, Matyjaszewski and co-workers first described controlled radical polymerization by Activators ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP),1-3 a developm...
Keywords: Antimicrobials, Ligands, Nanotubes, Oxidations, Polymerization reactions, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Solution polymerization, Solvents

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

Emergence of living radical polymerization mediated by transition metal catalysts in 1995 was a seminal piece of work in the field of synthetic polymer chemistry.1-3 Since this date, many transition ...
Keywords: Catalysis, Condensations, Evaporation, Filtration, Ligands, Oxidations, Polymer science, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Solvents

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Hua Wei1 and Suzie H. Pun2* 1Department of Chemistry, Lanzhou University, Lanzhou 730000 China 2Department of Bioengineering and Molecular Engineering and Sciences Institute University of Washington,...
Keywords: Aminolysis, Asymmetric synthesis, Bacterial conjugations, Biomaterials, Catalysis, Click chemistry, Cycloadditions, Degradations, Growth factors, Immobilization, Living polymerization, PAGE, Peptide synthesis, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Ring-opening polymerization, Solid phase peptide synthesis, Transfection, transformation

Typical Procedures for Polymerizing via ATRP

The following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.
Keywords: Gas chromatography, Ligands, Nuclear magnetic resonance spectroscopy, Polymerization reactions, Size-exclusion chromatography, Solvents

Peer-Reviewed Papers
15

References

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