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  • 73475 - (RP)-1-[(R)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

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73475 Sigma-Aldrich

(RP)-1-[(R)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene

optical purity ee: ≥99%

Synonym: (2S)-1-[(R)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS), Taniaphos SL-T001-1

  • CAS Number 1003012-96-1

  • Empirical Formula (Hill Notation) C43H39FeNP2

  • Molecular Weight 687.57

  •  PubChem Substance ID 24886571

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Solvias Ligands and Complexes,
Quality Level   100
optical purity   ee: ≥99%
storage temp.   2-8°C
SMILES string   [Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI   1S/C38H34NP2.C5H5.Fe/c1-39(2)38(35-27-17-29-37(35)41(32-22-11-5-12-23-32)33-24-13-6-14-25-33)34-26-15-16-28-36(34)40(30-18-7-3-8-19-30)31-20-9-4-10-21-31;1-2-4-5-3-1;/h3-29,38H,1-2H3;1-5H;/t38-;;/m1../s1
InChI key   DEHRMLQYTSYVBC-VROLVAQFSA-N

Description

General description

sold in collaboration with Solvias AG

Packaging

1, 5 g in glass bottle

100, 500 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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