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738883 Aldrich

1-Methyl-2-azaadamantane-N-oxyl Green Alternative

97%

Synonym: 1-Me-AZADO

  • CAS Number 872598-44-2

  • Empirical Formula (Hill Notation) C10H16NO

  • Molecular Weight 166.24

  •  PubChem Substance ID 329765308

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Properties

Related Categories 12 Principles Aligned Products, Amines, Building Blocks, C10, Chemical Synthesis,
InChI Key   IBNXYCCLPCGKDM-UHFFFAOYSA-N
assay   97%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   87-93 °C
storage temp.   2-8°C

Description

Packaging

25, 100 mg in clear glass bottle

Application

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO) may be employed as catalyst for the aerobic oxidation of alcohols and sterically hindered alcohols.

Catalytic oxidant for greener oxidation of alcohols under aerobic, solvent-free conditions. Recoverable and recyclable.

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

General description

1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO), a sterically less hindered nitroxyl radical, is widely used as catalyst. It is chemically stable and exhibits superior catalytic performance.

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Meet Synthia - Retrosynthesis Sofware
Protocols & Articles

Articles

TEMPO Catalyzed Oxidations

TEMPO (2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl) and its derivatives are stable nitroxy radicals used as catalysts in organic oxidation reactions. TEMPO was discovere...
Keywords: Aerobic, Capillary electrophoresis, Catalysis, Chromatography, Coupling reactions, Oxidations, Polymerization reactions, Size-exclusion chromatography, Solvents

Related Content

tempo催化氧化

TEMPO(2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基)及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现,其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。
Keywords: Capillary electrophoresis, Size-exclusion chromatography

Peer-Reviewed Papers
15

References

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