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741248 Sigma-Aldrich

Bis(triphenylphosphine)palladium(II) dichloride

Synonym: Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl2(PPh3)2

  • CAS Number 13965-03-2

  • Linear Formula [(C6H5)3P]2PdCl2

  • Molecular Weight 701.90

  •  Beilstein/REAXYS Number 4935975

  •  EC Number 237-744-2

  •  MDL number MFCD00009593

  •  PubChem Substance ID 329765477

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts, Phosphine Compounds,
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   Cl[Pd]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI   1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key   YNHIGQDRGKUECZ-UHFFFAOYSA-L

Description

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Bis(triphenylphosphine)palladium(II) dichloride is generally used as a catalyst for the synthesis of conjugated polymers via Stille coupling. It is also applicable to other coupling reactions such as Suzuki- and Sonogashira-coupling reactions

Packaging

1, 5, 25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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903124 (Ad−BippyPhos)2PdCl2

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