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743232 Aldrich

Sodium triflinate

≥95.0% (T)

Synonym: Langlois reagent, Sodium trifluoromethanesulfinate, Sodium trifluoromethylsulfinate, Trifluoromethanesulfinic acid sodium salt

  • CAS Number 2926-29-6

  • Empirical Formula (Hill Notation) CF3NaO2S

  • Molecular Weight 156.06

  •  Beilstein Registry Number 3723394

  •  MDL number MFCD03092989

  •  PubChem Substance ID 329765623

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Properties

Related Categories Building Blocks, Chemical Synthesis, Fluorination Reagents, Organic Building Blocks, Other Sulfur Compounds,
InChI Key   KAVUKAXLXGRUCD-UHFFFAOYSA-M
assay   ≥95.0% (T)
impurities   ≤1.0% water (Karl Fischer)
mp   <325 °C

Description

Application

Sodium triflinate (Langlois reagent) is a trifluoromethylating reagent used to incorporate trifluoromethyl groups onto aromatic and heteroaromatic moieties.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles

Articles

Baran Reagents FAQs

What do the Baran reagents do? Allow the placement of alkyl groups onto molecules in drug discovery by replacing a C-H bond with the corresponding C-C bond (trifluoromethyl, difluoromethyl, isopropyl...
Keywords: Agrochemicals, Alkylations, Drug discovery, Fluorinations, Liquid chromatography mass spectrometry, Medicinal chemistry, Nuclear magnetic resonance spectroscopy, PAGE, Solvents

Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization

While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a ...
Keywords: Catalysis, Cyclizations, Cycloadditions, Decarboxylations, Hydroaminations, Infrared spectroscopy, Oxidations

Protocols

Trifluoromethylation Kit

Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.
Keywords: Chromatography, Column chromatography, Gas chromatography, High performance liquid chromatography, Thin layer chromatography

Peer-Reviewed Papers
15

References

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