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745022 Sigma-Aldrich

9-Methyl-9H-fluorene-9-carbonyl chloride

≥99.0% (GC)

Synonym: 9-Methylfluorene-9-carbonyl chloride, COgen

  • CAS Number 82102-37-2

  • Empirical Formula (Hill Notation) C15H11ClO

  • Molecular Weight 242.70

  •  Beilstein/REAXYS Number 5266487

  •  MDL number MFCD18839248

  •  PubChem Substance ID 329765723

  •  NACRES NA.22

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Properties

assay   ≥99.0% (GC)
storage temp.   room temp
SMILES string   CC1(C(Cl)=O)c2ccccc2-c3ccccc13
InChI   1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3
InChI key   ZQYOOHGEBHBNTP-UHFFFAOYSA-N

Description

Application

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Linkage

Frequently Asked Questions are available for this Product.

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Application of Carbon Monoxide in Synthesis Made Simple and Safe by Prof. Skrydstrup and Coworkers

Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.1 The solid and bench stable CO-precursor, COgen, was found to be a highly efficie...
Keywords: Carbonylations, Heck Reaction, PAGE, Substitutions, Suzuki-Miyaura coupling

Skrydstrup Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Skrydstrup Group – Professor Product Portal
Keywords: Arylations, Carbonylations, Catalysis, Heck Reaction, Substitutions, Suzuki-Miyaura coupling

Peer-Reviewed Papers
15

References

Related Products

also commonly purchased with this product

Product #

Description

Add to Cart

745146 9-Methyl-9H-fluorene-9-carbonyl-13C chloride, ≥97.0% (GC)
743852 COware PTFE discs, for COware, screwable two-chamber glass sytem
743968 COware PTFE/silicone septa, for COware, screwable two-chamber glass sytem

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