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  • 745537 - 4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate

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745537 Sigma-Aldrich

4-(Acetylamino)-2,2,6,6-tetramethyl-1-oxo-piperidinium tetrafluoroborate

97% (HPLC)

Synonym: 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium tetrafluoroborate, Bobbitt′s Salt

  • CAS Number 219543-09-6

  • Empirical Formula (Hill Notation) C11H21BF4N2O2

  • Molecular Weight 300.10

  •  PubChem Substance ID 329764990

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Properties

Related Categories Chemical Synthesis, Oxidizing Agents, Peroxy Acids and Salts, Reproducibility: Validated Products, Synthetic Reagents,
InChI Key   HTMHEICBCHCWAU-UHFFFAOYSA-O
assay   97% (HPLC)
mp   191-197 °C (decomposition)
storage temp.   2-8°C

Description

Application

Bobbitt′s Salt is a stoiciometric oxidant, which is highly stable to both air and moisture. This reagent is highly robust in the oxidation of alcohols to their concomitant aldehyde, ketone or carboxylic acid. Most notable, is a recent publication shows the Bobbitt Salt is recyclable.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

James Bobbitt Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents James Bobbitt Group - Professor Product Portal
Keywords: Catalysis, Electron spin resonance, Materials Science, Oxidations

Photocatalysis

Visible light photoredox catalysis has emerged as a powerful tool in organic synthesis, building upon the foundation set by early pioneers in the areas of radical chemistry and photochemistry. Photor...
Keywords: Capillary electrophoresis, Catalysis, Cross couplings, Cycloadditions, Degradations, Drug discovery, Gas chromatography, Infrared spectroscopy, Organic synthesis, Oxidations, Reductions, Scintillation, transformation

Peer-Reviewed Papers
15

References

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