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746177 Sigma-Aldrich

MIBA

Green Alternative

96%

Synonym: 5-Methoxy-2-iodophenylboronic acid

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Properties

Related Categories 12 Principles Aligned Products, Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis,
assay   96%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   202-207 °C
storage temp.   2-8°C
SMILES string   OB(O)C1=C(I)C=CC(OC)=C1
InChI   1S/C7H8BIO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4,10-11H,1H3
InChI key   XQYAEIDOJUNIGY-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

MIBA can be used to promote direct amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Packaging

1 g in glass bottle

250 mg in glass insert

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Dennis Hall - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Dennis Hall - Professor Product Portal
Keywords: Addition reactions, Amidations, Asymmetric synthesis, Catalysis, Chemical biology, Grignard Reaction, Natural product synthesis, Solvents

Peer-Reviewed Papers
15

References

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