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746177 Aldrich

MIBA Green Alternative

96%

Synonym: 5-Methoxy-2-iodophenylboronic acid

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Properties

Related Categories 12 Principles Aligned Products, Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis,
InChI Key   XQYAEIDOJUNIGY-UHFFFAOYSA-N
assay   96%
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
mp   202-207 °C
storage temp.   2-8°C

Description

Packaging

1 g in glass bottle

250 mg in glass insert

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Application

MIBA can be used to promote direct amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

General description

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Dennis Hall - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Dennis Hall - Professor Product Portal
Keywords: Addition reactions, Amidations, Asymmetric synthesis, Catalysis, Chemical biology, Grignard Reaction, Natural product synthesis, Solvents

Peer-Reviewed Papers
15

References

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