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746304 Sigma-Aldrich

S,S-Dibenzyl trithiocarbonate

97%

Synonym: Carbonic acid, trithio-, dibenzyl ester, Carbonotrithioic acid bis(phenylmethyl) ester, DBTTC, Dibenzyl carbonotrithioate, NSC 33081

  • CAS Number 26504-29-0

  • Empirical Formula (Hill Notation) C15H14S3

  • Molecular Weight 290.47

  •  MDL number MFCD12911902

  •  PubChem Substance ID 329765756

  •  NACRES NA.23

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Properties

Related Categories Materials Science, Polymer Science, RAFT Agents, Reagents for Controlled Radical Polymerization, Reagents for Polymerization,
Quality Level   100
assay   97%
mp   29-33 °C
storage temp.   2-8°C
SMILES string   S=C(SCC1=CC=CC=C1)SCC2=CC=CC=C2
InChI   1S/C15H14S3/c16-15(17-11-13-7-3-1-4-8-13)18-12-14-9-5-2-6-10-14/h1-10H,11-12H2
InChI key   LAKYXBYUROTWBI-UHFFFAOYSA-N

Description

Packaging

1, 5 g in glass bottle

Application

Trithiocarbonate-based RAFT agent used as a bifunctional Chain Transfer Agent (CTA) in RAFT polymerization of block copolymers for drug delivery. Provides good control of polymerization of vinyl monomers, including styrene, methacrylate, and acrylamide.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Hua Wei1 and Suzie H. Pun2* 1Department of Chemistry, Lanzhou University, Lanzhou 730000 China 2Department of Bioengineering and Molecular Engineering and Sciences Institute University of Washington,...
Keywords: Aminolysis, Asymmetric synthesis, Bacterial conjugations, Biomaterials, Catalysis, Click chemistry, Cycloadditions, Degradations, Growth factors, Immobilization, Living polymerization, PAGE, Peptide synthesis, Polymerization reactions, Precipitation, Purification, Radical polymerization, Reductions, Reversible addition-fragmentation chain transfer polymerizations, Ring-opening polymerization, Solid phase peptide synthesis, Transfection, transformation

Protein and Peptide Polymer Conjugates

1Department of Chemistry, The University of Warwick, Coventry CV4 7AL, U.K. 2Warwick Medical School, The University of Warwick, Coventry CV4 7AL, U.K. 3Faculty of Pharmacy and Pharmaceutical Sciences...
Matthias Hartlieb,1 Raoul Peltier,1 Sébastien Perrier1,2,3*
Material Matters, 2017, 12.2
Keywords: Aminolysis, Bacterial conjugations, Biological processes, Biomaterials, Click chemistry, Cycloadditions, Degradations, Gene expression, Growth factors, Immobilization, Michael Addition, Nanotubes, PEGylations, Peptide synthesis, Pharmaceutical, Polymerization reactions, Post translational modifications, Purification, Radical polymerization, Reversible addition-fragmentation chain transfer polymerizations, Solid phase peptide synthesis, Solvents

Select RAFT Agents for Making Well-Defined Functionalized Polymers

The supply of low cost, high purity and effective Reversible addition−fragmentation chain-transfer (RAFT) Agents is the essential element in the industrial implementation of RAFT polymerization techn...
Liz G. Williamsa, Ken Sullivanb and John Tsanaktsidisa

a CSIRO Manufacturing, Ian Wark Laboratory, Bayview Avenue, Clayton, Victoria 3168, Australia, and
b Boron Molecular INC, 2650-110 Discovery Drive, Raleigh, NC 27616 USA
Keywords: Polymerization reactions, Reversible addition-fragmentation chain transfer polymerizations

Peer-Reviewed Papers
15

References

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