EMAIL THIS PAGE TO A FRIEND
747777 Sigma-Aldrich

[Ru(bpz)3][PF6]2

95%

Synonym: Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate), Tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate

  • CAS Number 80907-56-8

  • Empirical Formula (Hill Notation) C24H18F12N12P2Ru

  • Molecular Weight 865.48

  •  NACRES NA.22

Purchase

Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Photocatalysis, Ruthenium Catalysts
Quality Level   100
assay   95%
impurities   may contain ca. 5% acetonitrile
mp   162-210 °C (The MP data is a DECOMP) (lit.)
SMILES string   [N]12=CC=NC=C1C3=CN=CC=[N]3[Ru]24([N]5=CC=NC=C5C6=CN=CC=[N]64)([N]7=CC=NC=C78)[N]9=C8C=NC=C9
InChI   1S/3C8H6N4.Ru/c3*1-3-11-7(5-9-1)8-6-10-2-4-12-8;/h3*1-6H;
InChI key   VEEMVPAUPIJPLA-UHFFFAOYSA-N

Description

General description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

Application

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Packaging

50, 100 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

Please Enter a Lot Number
Protocols & Articles

Related Content

Lab Chemicals

From our library of Related Content, Sigma-Aldrich presents Lab Chemicals
Keywords: Gas chromatography, Infrared spectroscopy, Sublimation, Thin layer chromatography

Peer-Reviewed Papers
15

References

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?