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747793 Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Synonym: [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate, [Ir{dF(CF3)ppy}2(dtbpy)]PF6

  • CAS Number 870987-63-6

  • Empirical Formula (Hill Notation) C42H34F16IrN4P

  • Molecular Weight 1121.91

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts, Photocatalysis
Quality Level   100
mp   >300 °C
reaction suitability   reagent type: catalyst
reaction type: Photocatalysis
SMILES string   F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

Description

Application

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.

Packaging

1 g in glass bottle

100 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Photocatalysis

Visible light photoredox catalysis has emerged as a powerful tool in organic synthesis, building upon the foundation set by early pioneers in the areas of radical chemistry and photochemistry. Photor...
Keywords: Capillary electrophoresis, Catalysis, Cross couplings, Cycloadditions, Degradations, Drug discovery, Gas chromatography, Infrared spectroscopy, Organic synthesis, Oxidations, Reductions, Scintillation, transformation

Stephenson Group – Professor Product Portal

Professor Corey Stephenson Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions. Specifical...
Keywords: Catalysis, Infrared spectroscopy, Materials Science, Natural product synthesis

Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

Add to Cart

901368 [Ir(dFppy)2(dtbbpy)]PF6
901409 [Ir(dF(Me)ppy)2(dtbbpy)]PF6
902217 Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%
902225 Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%
904694 Ir(p-CF3-ppy)3, ≥95%
905518 Ir(dFFppy)2(dtbbpy)PF6
905917 (Ir[Me(Me)ppy]2(dtbpy))PF6
908568 [Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6, ≥95%
908703 [Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

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