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751413 Sigma-Aldrich

Di(1-adamantyl)-2-dimethylaminophenylphosphine

98%

Synonym: 2-(Di-1-adamantylphosphino)-N,N-dimethylaniline, 2-(Di-1-adamantylphosphino)dimethylaminobenzene, 2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine, Me-Dalphos

  • CAS Number 1219080-77-9

  • Empirical Formula (Hill Notation) C28H40NP

  • Molecular Weight 421.60

  •  MDL number MFCD17018758

  •  PubChem Substance ID 329766214

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   98%
mp   237-242 °C
functional group   phosphine
reaction suitability   reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
SMILES string   CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
InChI   1S/C28H40NP/c1-29(2)25-5-3-4-6-26(25)30(27-13-19-7-20(14-27)9-21(8-19)15-27)28-16-22-10-23(17-28)12-24(11-22)18-28/h3-6,19-24H,7-18H2,1-2H3/t19-,20+,21-,22-,23+,24-,27-,28-
InChI key   MILNYLCUWRWYBI-XMCXLQRDSA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

DalPhos Ligands

Professor Mark Stradiotto and coworkers at Dalhousie University have developed air-stable Dalphos, which contains the bulky di(1-adamantyl)phosphino [P(1-Ad)2] fragment. These chelating N,P ligands a...
Keywords: Arylations, C-C bond formation, Catalysis, Cross couplings, Hydroaminations, Ligands

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

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