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751618 Sigma-Aldrich

MorDalphos

97%

Synonym: Di(1-adamantyl)-2-morpholinophenylphosphine

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Properties

Related Categories Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
InChI Key   CCBRRSUORFMQCZ-BVIFAWIJSA-N
assay   97%
mp   219-224 °C
reaction suitability   reagent type: ligand
reaction type: Arylations
  reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
storage temp.   2-8°C

Description

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

Application

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

DalPhos Ligands

Professor Mark Stradiotto and coworkers at Dalhousie University have developed air-stable Dalphos, which contains the bulky di(1-adamantyl)phosphino [P(1-Ad)2] fragment. These chelating N,P ligands a...
Keywords: Arylations, C-C bond formation, Catalysis, Cross couplings, Hydroaminations, Ligands

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

Peer-Reviewed Papers
15

References

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