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751618 Sigma-Aldrich

MorDalphos

97%

Synonym: Di(1-adamantyl)-2-morpholinophenylphosphine

  • CAS Number 1237588-12-3

  • Empirical Formula (Hill Notation) C30H42NOP

  • Molecular Weight 463.63

  •  MDL number MFCD17018759

  •  PubChem Substance ID 329766227

  •  NACRES NA.22

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Properties

Related Categories Buchwald Ligands and Complexes, Buchwald and Related Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Quality Level   100
assay   97%
mp   219-224 °C
functional group   phosphine
reaction suitability   reagent type: ligand
reaction type: Arylations
  reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
storage temp.   2-8°C
SMILES string   C1CN(CCO1)c2ccccc2P([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
InChI   1S/C30H42NOP/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30/h1-4,21-26H,5-20H2/t21-,22+,23-,24-,25+,26-,29-,30-
InChI key   CCBRRSUORFMQCZ-BVIFAWIJSA-N

Description

Application

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

Packaging

1, 5 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

DalPhos Ligands

Professor Mark Stradiotto and coworkers at Dalhousie University have developed air-stable Dalphos, which contains the bulky di(1-adamantyl)phosphino [P(1-Ad)2] fragment. These chelating N,P ligands a...
Keywords: Arylations, C-C bond formation, Catalysis, Cross couplings, Hydroaminations, Ligands

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

Peer-Reviewed Papers
15

References

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