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  • 752231 - 2-[2-(Dicyclohexylphosphino)phenyl]-N-methylindole

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752231 Sigma-Aldrich

2-[2-(Dicyclohexylphosphino)phenyl]-N-methylindole

97%

Synonym: 2-[2-(Dicyclohexylphosphino)phenyl]-1-methyl-1H-indole, CM-Phos

  • CAS Number 1067883-58-2

  • Empirical Formula (Hill Notation) C27H34NP

  • Molecular Weight 403.54

  •  MDL number MFCD16995285

  •  PubChem Substance ID 329766273

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C13 to C27, Catalysis and Inorganic Chemistry, Chemical Synthesis, Heterocyclic Building Blocks,
assay   97%
mp   180-185 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   Cn1c(cc2ccccc12)-c3ccccc3P(C4CCCCC4)C5CCCCC5
InChI   1S/C27H34NP/c1-28-25-18-10-8-12-21(25)20-26(28)24-17-9-11-19-27(24)29(22-13-4-2-5-14-22)23-15-6-3-7-16-23/h8-12,17-20,22-23H,2-7,13-16H2,1H3
InChI key   PFJAHDIIEPTASS-UHFFFAOYSA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

A Mild and Efficient Palladium-Catalyzed Cyanation of Aryl Chlorides with K4[Fe(CN)6]

The cross-coupling reactions of allylboronic acid pinacol ester derivatives with aryl and heteroaryl halides occurred with high selectivity (>97%) at the ?-carbon of the allylboron reagent in the pre...
Keywords: Chromatography, Coupling reactions, Cross couplings, Flash chromatography

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