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754730 Sigma-Aldrich

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate

97%

Synonym: Ru(bpy)3(PF6)2, Ruthenium-tris(2,2′-bipyridyl) dihexafluorophosphate

  • CAS Number 60804-74-2

  • Empirical Formula (Hill Notation) C30H24F12N6P2Ru

  • Molecular Weight 859.55

  •  MDL number MFCD11042502

  •  PubChem Substance ID 329766452

  •  NACRES NA.23

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Light Emitters and Dopants, Materials Science, OLED and PLED Materials,
Quality Level   100
assay   97%
impurities   (Material is not fluorescence active.)
mp   >300 °C
absorption   13,400 at 456 nm
  80,000 at 291 nm
SMILES string   [Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6
InChI   1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2
InChI key   KLDYQWXVZLHTKT-UHFFFAOYSA-N

Description

General description

Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate (Ru(bpy)3(PF6)2) is a conducting polymer that is majorly used as an active layer in electrochemical devices. It facilitates the formation of highly efficient and low voltage devices. It shows an external quantum efficiency of 0.35 and 400 cd/m2 at 3V.

Application

Ru(bpy)3(PF6)2 may be used as a conjugating polymer in the development of light emitting electrochemical cell based devices such as light emitting diodes (LEDs).

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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