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758388 Sigma-Aldrich

Pyrazino[2,3-f][1,10]phenanthroline

99% (HPLC)

  • CAS Number 217-90-3

  • Empirical Formula (Hill Notation) C14H8N4

  • Molecular Weight 232.24

  •  MDL number MFCD18447748

  •  PubChem Substance ID 329766739

  •  NACRES NA.23

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Properties

Related Categories Ligands and Metal Complex Precursors, Materials Science, Organic and Printed Electronics, Synthetic Tools and Reagents
Quality Level   100
assay   99% (HPLC)
mp   310-315 °C
SMILES string   c1cnc2c(c1)c3nccnc3c4cccnc24
InChI   1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H
InChI key   IBOSPAWVGHGUAV-UHFFFAOYSA-N

Description

General description

Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.

Application

• As an electron accepting ligand in metal complexes which are used in solar cells.
• Used in the synthesis of ruthenium (II) complexes which are used as DNA probes.

Packaging

1 g in glass bottle

Features and Benefits

Imparts improved directionality of electron transfer in excited copper complexes.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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