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760838 Sigma-Aldrich

Allyl tetraisopropylphosphorodiamidite

95%

  • CAS Number 108554-72-9

  • Linear Formula [[(CH3)2CH]2N]2POCH2CH=CH2

  • Molecular Weight 288.41

  •  MDL number MFCD00191714

  •  PubChem Substance ID 329766898

  •  NACRES NA.22

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Properties

Related Categories Chemical Biology, Chemical Synthesis, Coupling Reagents, Nucleoside Chemistry
Quality Level   100
assay   95%
refractive index   n20/D 1.466 (lit.)
  n20/D 1.467
bp   114-117 °C/0.4 mmHg (lit.)
density   0.903 g/mL at 25 °C (lit.)
  0.910 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   CC(C)N(C(C)C)P(OCC=C)N(C(C)C)C(C)C
InChI   1S/C15H33N2OP/c1-10-11-18-19(16(12(2)3)13(4)5)17(14(6)7)15(8)9/h10,12-15H,1,11H2,2-9H3
InChI key   ZTEGHJIXOZLSOH-UHFFFAOYSA-N

Description

Application

Allyl tetraisopropylphosphorodiamidite may be used in the total synthesis of (−)-tetrahydrolipstatin, dolabelide C, (-)-salicylihalamides A and B.

Phosphitylation agent used in the preparation of oligonucleotides. Selective deallylation is accomplished by palladium catalysis.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NA 1993 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
188.0 °F
Flash Point(C) 
86.67 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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