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  • 761397 - (S)-(4,4′,6,6′-Tetramethoxybiphenyl -2,2′-diyl)bis(bis(3,5-dimethylphenyl )phosphine)

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761397 Sigma-Aldrich

(S)-(4,4′,6,6′-Tetramethoxybiphenyl -2,2′-diyl)bis(bis(3,5-dimethylphenyl )phosphine)

97%

Synonym: (S)-Xyl-Garphos

  • CAS Number 1365531-90-3

  • Empirical Formula (Hill Notation) C48H52O4P2

  • Molecular Weight 754.87

  •  MDL number MFCD19443624

  •  PubChem Substance ID 329766933

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   97%
optical activity   [α]22/D -87.0, c = 0.5% in chloroform
mp   >300 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   COc1cc(OC)c(c(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)-c4c(OC)cc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6
InChI   1S/C48H52O4P2/c1-29-13-30(2)18-39(17-29)53(40-19-31(3)14-32(4)20-40)45-27-37(49-9)25-43(51-11)47(45)48-44(52-12)26-38(50-10)28-46(48)54(41-21-33(5)15-34(6)22-41)42-23-35(7)16-36(8)24-42/h13-28H,1-12H3
InChI key   IDNKFBDRZBLTFQ-UHFFFAOYSA-N

Description

Packaging

100, 500 mg in glass bottle

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Garphos is a trademark of Kanata Chemical Technologies, Inc.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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