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763268 Sigma-Aldrich

1-Methyl-2-(2-diphenylphosphinophenyl)-1H-benzoimidazole

95%

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   95%
mp   166-172 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
storage temp.   20-25°C
SMILES string   Cn1c(nc2ccccc12)-c3ccccc3P(c4ccccc4)c5ccccc5
InChI   1S/C26H21N2P/c1-28-24-18-10-9-17-23(24)27-26(28)22-16-8-11-19-25(22)29(20-12-4-2-5-13-20)21-14-6-3-7-15-21/h2-19H,1H3
InChI key   BVVIYNVQLLTULW-UHFFFAOYSA-N

Description

Packaging

2 g in glass bottle

500 mg in glass bottle

Application

Efficient ligand for Suzuki-Miyaura coupling with of aryl mesylates and Buchwald-Hartwig amination with aryl chlorides.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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