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764299 Sigma-Aldrich

APhos Pd G2

Synonym: APhos-Pd-G2, Chloro[4-(di-tert-butylphosphino)-N,N-dimethylaniline-2-(2′-aminobiphenyl)]palladium(II)

  • CAS Number 2169976-34-3

  • Empirical Formula (Hill Notation) C28H38ClN2PPd

  • Molecular Weight 575.46

  •  MDL number MFCD22417237

  •  PubChem Substance ID 329767111

  •  NACRES NA.22

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Properties

Related Categories Buchwald 2nd Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Quality Level   100
impurities   <2% Acetone
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string   Nc1ccccc1-c2ccccc2[Pd]Cl.CN(C)c3ccc(cc3)P(C(C)(C)C)C(C)(C)C
InChI   1S/C16H28NP.C12H10N.ClH.Pd/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h9-12H,1-8H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key   LRWGTPCCIGPYMI-UHFFFAOYSA-M

Description

Packaging

2 g in glass bottle

500 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stephen Buchwald Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stephen Buchwald Group – Professor Product Portal
Keywords: Aminations, Asymmetric catalysis, Asymmetric synthesis, Catalysis, Coupling reactions, Cross couplings, Fluorinations, Ligands, Solvents, transformation

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903728 DavePhos Pd G2

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