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767441 Sigma-Aldrich

Potassium [(4-methoxybenzyloxy)methyl]trifluoroborate

97%

  • CAS Number 1027642-26-7

  • Empirical Formula (Hill Notation) C9H11BF3KO2

  • Molecular Weight 258.09

  •  MDL number MFCD11505925

  •  PubChem Substance ID 329767313

  •  NACRES NA.22

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Properties

Related Categories Aryl Trifluoroborate Salts, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trifluoroborate Salts More...
Quality Level   100
assay   97%
mp   203-213 °C
SMILES string   [K+].COc1ccc(COC[B-](F)(F)F)cc1
InChI   1S/C9H11BF3O2.K/c1-14-9-4-2-8(3-5-9)6-15-7-10(11,12)13;/h2-5H,6-7H2,1H3;/q-1;+1
InChI key   HWHMOMQODHUMRW-UHFFFAOYSA-N

Description

Application

Alkoxymethyltrifluoroborate undergoes palladium-catalyzed carbon-carbon bond formation (Suzuki-Miyuara reaction) with aryl chlorides to provide a non-traditional disconnection for the preparation of aryl- and heteroaryl ethers.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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