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  • 768189 - {4-[2-Di(1-adamantyl)phosphino]phenylmorpholine}gold(I) bis(trifluoromethanesulfonyl)imide

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768189 Sigma-Aldrich

{4-[2-Di(1-adamantyl)phosphino]phenylmorpholine}gold(I) bis(trifluoromethanesulfonyl)imide

97%

Synonym: Mor-DalPhos-AuNTf2

  • CAS Number 1631714-76-5

  • Empirical Formula (Hill Notation) C32H42AuF6N2O5PS2

  • Molecular Weight 940.75

  •  PubChem Substance ID 329767361

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
assay   97%
reaction suitability   core: gold
  reagent type: catalyst
impurities   ~1% dichloromethane
mp   201-219 °C (decomposition)
SMILES string   FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.C1CN(CCO1)c2ccccc2P(C34CC5CC(CC(C5)C3)C4)C67CC8CC(CC(C8)C6)C7
InChI   1S/C30H42NOP.C2F6NO4S2.Au/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h1-4,21-26H,5-20H2;;/q;-1;+1
InChI key   KBBIHJFOPXAUCY-UHFFFAOYSA-N

Description

Packaging

100, 500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

Zhang Group - Professor Product Portal Index

From our library of Articles, Sigma-Aldrich presents Zhang Group - Professor Product Portal Index
Keywords: Catalysis, Coupling reactions, Cross couplings, Cycloadditions, Ligands, Natural product synthesis, Oxidations, Redox Reactions

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