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768219 Sigma-Aldrich

(Acetonitrile)[di(1-adamantyl)-2-dimethylaminophenylphosphine]gold(I) hexafluoroantimonate

Synonym: Me-Dalphos-AuMeCN SbF6

  • Empirical Formula (Hill Notation) C30H43AuF6N2PSb

  • Molecular Weight 895.37

  •  PubChem Substance ID 329767364

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Gold Catalysts, Gold Complexes
reaction suitability   core: gold
  reagent type: catalyst
mp   71-96 °C (decomposition)
SMILES string   CC#[N+][Au].F[Sb-](F)(F)(F)(F)F.CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6
InChI   1S/C28H40NP.C2H3N.Au.6FH.Sb/c1-29(2)25-5-3-4-6-26(25)30(27-13-19-7-20(14-27)9-21(8-19)15-27)28-16-22-10-23(17-28)12-24(11-22)18-28;1-2-3;;;;;;;;/h3-6,19-24H,7-18H2,1-2H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6/t19-,20+,21-,22-,23+,24-,27-,28-;;;;;;;;;
InChI key   KDIFRMWEKWQRPP-NIJDDVSFSA-H

Description

Packaging

100, 500 mg in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

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