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771880 Sigma-Aldrich

Bis(bicyclo[2.2.1]-2-heptyl)chloroborane

Synonym: Bis-norbornylchloroborane

  • CAS Number 137495-66-0

  • Empirical Formula (Hill Notation) C14H22BCl

  • Molecular Weight 236.59

  •  PubChem Substance ID 329767523

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Deprotonation
refractive index   n20/D 1.517
bp   131-136 °C/760 mmHg (decomposition)
density   1.058 g/mL at 25 °C
storage temp.   2-8°C
SMILES string   ClB(C1C[C@@H]2CC[C@H]1C2)C3C[C@@H]4CC[C@H]3C4
InChI   1S/C14H22BCl/c16-15(13-7-9-1-3-11(13)5-9)14-8-10-2-4-12(14)6-10/h9-14H,1-8H2/t9-,10-,11+,12+,13?,14?/m1/s1
InChI key   FIZRDRGODZJEDW-NXAPOWPLSA-N

Description

Application

Reagent promotes diastereoselective syn-aldol products from beta-gamma unsaturated propanoates.

Packaging

5 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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