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772976 Sigma-Aldrich

Di(1-adamantyl)-(2-triisopropylsiloxyphenyl)phosphine

97%

Synonym: OTIPS-DalPhos

  • CAS Number 1384966-55-5

  • Empirical Formula (Hill Notation) C35H55OPSi

  • Molecular Weight 550.87

  •  MDL number MFCD23098736

  •  PubChem Substance ID 329767591

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
assay   97%
mp   218-223 °C
functional group   phosphine
reaction suitability   reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
SMILES string   CC(C)[Si](Oc1ccccc1P([C@]23C[C@H]4C[C@H](C[C@H](C4)C2)C3)[C@]56C[C@H]7C[C@H](C[C@H](C7)C5)C6)(C(C)C)C(C)C
InChI   1S/C35H55OPSi/c1-23(2)38(24(3)4,25(5)6)36-32-9-7-8-10-33(32)37(34-17-26-11-27(18-34)13-28(12-26)19-34)35-20-29-14-30(21-35)16-31(15-29)22-35/h7-10,23-31H,11-22H2,1-6H3/t26-,27+,28-,29-,30+,31-,34-,35-
InChI key   LAQRMRNBWOVSBV-QDACEEAESA-N

Description

Packaging

1 g in glass bottle

250 mg in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stradiotto Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stradiotto Group – Professor Product Portal
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Hydroaminations, Ligands

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