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776270 Sigma-Aldrich

n-Propylmagnesium chloride solution

Green Alternative

1.0 M in 2-methyltetrahydrofuran

Synonym: Propylmagnesium chloride solution

  • CAS Number 2234-82-4

  • Linear Formula CH3CH2CH2MgCl

  • Molecular Weight 102.85

  •  Beilstein/REAXYS Number 3600246

  •  MDL number MFCD00000474

  •  PubChem Substance ID 329767827

  •  NACRES NA.22

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Properties

Related Categories 12 Principles Aligned Products, 25mL Sure/Seal Reagents, Alkyl, Aryl and Alkenyl - Grignard reagent, Chemical Synthesis, Greener Alternative Products,
reaction suitability   reaction type: Grignard Reaction
greener alternative product characteristics   Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
concentration   1.0 M in 2-methyltetrahydrofuran
density   0.896 g/mL at 25 °C
greener alternative category   Aligned
SMILES string   CCC[Mg]Cl
InChI   1S/C3H7.ClH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q;;+1/p-1
InChI key   AMXVKMXLDJXAPM-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

4×25, 100, 800 mL in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
WGK 2
Flash Point(F) 
-22.0 °F - closed cup
Flash Point(C) 
-30 °C - closed cup

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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