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  • 77939 - (R)-3,3′-Di-tert-butyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-(bi-2-naphthol) dipotassium salt

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77939 Sigma-Aldrich

(R)-3,3′-Di-tert-butyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-(bi-2-naphthol) dipotassium salt

purum, ≥95.0% (dry substance, CHN)

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Properties

Related Categories Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
grade   purum
assay   ≥95.0% (dry substance, CHN)
impurities   <10% water
SMILES string   [K+].[K+].CC(C)(C)c1cc2CCCCc2c(c1[O-])-c3c([O-])c(cc4CCCCc34)C(C)(C)C
InChI   1S/C28H38O2.2K/c1-27(2,3)21-15-17-11-7-9-13-19(17)23(25(21)29)24-20-14-10-8-12-18(20)16-22(26(24)30)28(4,5)6;;/h15-16,29-30H,7-14H2,1-6H3;;/q;2*+1/p-2
InChI key   KUFMCCDFHGQYSN-UHFFFAOYSA-L

Description

Application

Octahydro-BINOL was demonstrated to be an effective ligand in Mo-catalyzed desymmetrization of a triene by asymmetric ring closing metathesis.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

A readily available user-friendly chiral catalyst for efficient enantioselective olefin metathesis, used in conjunction with Cat. No. 75287, a molybdenum complex

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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