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790397 Sigma-Aldrich

Potassium 2-bromo-4-(trifluoromethyl)pyridine-3-trifluoroborate

  • Empirical Formula (Hill Notation) C6H2BBrF6KN

  • Molecular Weight 331.89

  •  MDL number MFCD27978255

  •  PubChem Substance ID 329768211

  •  NACRES NA.22

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Properties

Related Categories Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Trifluoroborate Salts, Organometallic Reagents, Trifluoroborate Salts More...
Quality Level   100
assay   97%
SMILES string   BrC1=C([B-](F)(F)F)C(C(F)(F)F)=CC=N1.[K+]
InChI   1S/C6H2BBrF6N.K/c8-5-4(7(12,13)14)3(1-2-15-5)6(9,10)11;/h1-2H;/q-1;+1
InChI key   WGDRKFJAJWNHQI-UHFFFAOYSA-N

Description

Application

An organotrifluoroborate involved in:
• Nickel-catalyzed cross-coupling reactions and C-O activation
• Suzuki cross-coupling,
• Copper-catalyzed cross-coupling reactions
• Stereoselective Mukaiyama aldol reactions

Organotrifluoroborates as versatile and stable boronic acid surrogates.

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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