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792187 Sigma-Aldrich

Zinc bis[(phenylsulfonyl)methanesulfinate]

95% (H-NMR)

Synonym: Baran PSMS Reagent

  • Empirical Formula (Hill Notation) C14H14O8S4Zn

  • Molecular Weight 503.91

  •  MDL number MFCD28016341

  •  PubChem Substance ID 329768318

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Properties

Related Categories Alkyl Diversinates, Baran Diversinates, C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis,
InChI Key   NUNOSEKSQAHHKH-UHFFFAOYSA-L
assay   95% (H-NMR)
form   solid
storage temp.   2-8°C

Description

Packaging

1 g in glass bottle

Application

New reagent is inspired by nature′s methylating agent, S-adenosyl methionine (SAM). Nitrogen-containing heterocycles can be effectively methylated through a routine two-step route.

C–H Methylation of Heteroarenes Inspired by Radical SAM Methyl Transferase

Profound Methyl Effects in Drug Discovery and a Call for New C H Methylation Reactions

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Diversinates™: Any-Stage Functionalization of (Hetero)aromatic Scaffolds

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. With the ever-growing demand of new chemical entities coupled to the dwindling resources and time cons...
Keywords: Alkylations, Catalysis, Chemical industry, Cross couplings, PAGE

Professor Product Portal - Baran Group

From our library of Articles, Sigma-Aldrich presents Professor Product Portal - Baran Group
Keywords: Building blocks, Fluorinations, Oxidations, Pharmaceutical

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