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794171 Sigma-Aldrich

9-Mesityl-10-methylacridinium tetrafluoroborate

Synonym: 10-Methyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate, 9-Mesityl-10-methylacridinium tetrafluoroborate

  • CAS Number 1442433-71-7

  • Empirical Formula (Hill Notation) C23H22BF4N

  • Molecular Weight 399.23

  •  PubChem Substance ID 329768429

  •  NACRES NA.22

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Properties

Related Categories Acridinium Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Photocatalysis
Quality Level   100
reaction suitability   reagent type: catalyst
SMILES string   CC(C=C1C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.F[B-](F)(F)F
InChI   1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1
InChI key   KKMWMXQQOIIJIZ-UHFFFAOYSA-N

Description

Application

Catalyst has been reported by Nicewicz and coworkers to mediate myriad transformations through Photoredox Catalysis. The following applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent (Aldrich 743232).

Packaging

1 g in glass bottle

250 mg in glass bottle

Other Notes

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes

Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

David Nicewicz Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents David Nicewicz Group - Professor Product Portal
Keywords: Addition reactions, Catalysis, Cycloadditions, Hydroaminations, Infrared spectroscopy, Oxidations

Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization

While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a ...
Keywords: Catalysis, Cyclizations, Cycloadditions, Decarboxylations, Hydroaminations, Infrared spectroscopy, Oxidations

Related Products

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Product #

Description

Add to Cart

900693 9-Mesityl-1,3,6,8-tetramethoxy-10-phenylacridin-10-ium tetrafluoroborate, 95%
900694 10-(3,5-Dimethoxyphenyl)-9-mesityl-1,3,6,8-tetramethoxyacridin-10-ium tetrafluoroborate, ≥95%
906115 2,7-Dibromoacridone
909033 2,7-Dibromo-9-mesityl-10-methylacridinium tetrafluoroborate
909181 2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate
909254 2,7-Difluoro-9-mesityl-10-methylacridinium tetrafluoroborate
909319 2,7-Dibromo-10-methylacridone, ≥95%
909327 2,7-Dimethoxy-9-mesityl-10-methylacridinium tetrafluoroborate

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