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797693 Sigma-Aldrich

2-Chloro-6-(trimethylsilyl)phenyl triflate

95%

Synonym: Garg 3-chlorobenzyne precursor

  • CAS Number 1449472-59-6

  • Empirical Formula (Hill Notation) C10H12ClF3O3SSi

  • Molecular Weight 332.80

  •  PubChem Substance ID 329768621

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Pyridyne and Indolyne Precursors
InChI Key   QFWUIGWOSVHZMC-UHFFFAOYSA-N
assay   95%
storage temp.   2-8°C

Description

Packaging

1 g in glass insert

250 mg in amber glass bottle

Application

Chlorosilyltriflate has been shown to be a useful precursor for the generation of a chlorobenzyne intermediate. The chlorobenzyne intermediate can be generated in the presence of Cesium or Potassium Fluoride and can be trapped with various dipolariphiles.

Other Notes

Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport

Documents

Certificate of Analysis

Certificate of Origin


Meet Synthia - Retrosynthesis Sofware
Protocols & Articles

Articles

Neil Garg Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Neil Garg Group - Professor Product Portal
Keywords: Addition reactions, Building blocks, Catalysis, Cycloadditions, Nucleophilic additions, Pharmaceutical

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