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798061 Sigma-Aldrich

(3E)-4-Phenylbut-3-enoic acid methyl ester

Synonym: Methyl (3E)-4-Phenylbut-3-enoate, Methyl (E)-4-phenylbut-3-enoate, Methyl trans-styryl acetate

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Properties

Quality Level   100
storage temp.   2-8°C
SMILES string   O=C(OC)C/C=C/C1=CC=CC=C1
InChI   1S/C11H12O2/c1-13-11(12)9-5-8-10-6-3-2-4-7-10/h2-8H,9H2,1H3/b8-5+
InChI key   VOEDRUGFNJEWGQ-VMPITWQZSA-N

Description

Application

Building block is reported by Huw Davies and coworkers as a precursor to the 2013 EROS Best Reagent; Methyl (E)-4-Phenyl-2-diazo-3-butenoate. Methyl (E)-4-Phenyl-2-diazo-3-butenoate is a donor-acceptor precursor to the corresponding Ru-carbenoid that is utilized in C-H insertion and cyclopropanation reactions.

Packaging

1, 10 g in glass bottle

Preparation Note

Preparatory information to make (E)-4-Phenyl-2-diazo-3-butenoate can be found by clicking the link below under other notes.

Other Notes

Methyl 2-Diazo-3-butenoate

Safety & Documentation

Safety Information

Symbol 
GHS09  GHS09
Hazard statements 
Precautionary statements 
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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