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798711 Sigma-Aldrich

(R)-Xyl-SDP(O)

Synonym: (R)-Xyl-SDP Oxide, [(1R)-7′-[Bis(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobi[1H-inden]-7-yl]bis(3,5-dimethylphenyl)phosphine oxide

  • CAS Number 1462321-89-6

  • Empirical Formula (Hill Notation) C49H50OP2

  • Molecular Weight 716.87

  •  PubChem Substance ID 329768666

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Solvias Ligands and Complexes More...
Quality Level   100
assay   ≥95%
storage temp.   2-8°C
SMILES string   CC1=CC(C)=CC(P(C2=CC(C)=CC(C)=C2)(C3=CC=CC4=C3[C@]5(CCC6=C5C(P(C7=CC(C)=CC(C)=C7)C8=CC(C)=CC(C)=C8)=CC=C6)CC4)=O)=C1
InChI   1S/C49H50OP2/c1-31-19-32(2)24-41(23-31)51(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)52(50,43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3/t49-/m1/s1
InChI key   ZAQVAUFRFBAVHF-ANFMRNGASA-N

Description

Application

Chiral ligand introduced in collaboration with Prof. Steve Zhou and coworkers, has shown utility in asymmetric Heck reactions for both intra and intermolecular C-C bond formation with various triflates and halides.

Packaging

50 mg in glass bottle

Other Notes

Palladium-Catalyzed Asymmetric Intermolecular Cyclization

Asymmetric Intermolecular Heck Reaction of Aryl Halides

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Zhou Group - Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Zhou Group - Professor Product Portal
Keywords: Arylations, Asymmetric synthesis, C-C bond formation, Catalysis, Heck Reaction, Substitutions, Vinylations

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