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  • 798819 - (S)-N-Butyl-1-[(S)-2-((E)-2-hydroxybenzylideneamino)-3-methylbutanoyl]pyrrolidine-2-carboxamide

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798819 Sigma-Aldrich

(S)-N-Butyl-1-[(S)-2-((E)-2-hydroxybenzylideneamino)-3-methylbutanoyl]pyrrolidine-2-carboxamide

Synonym: Yoon Anti-[2+2]-Photocycloaddition Ligand

  • CAS Number 1613249-59-4

  • Empirical Formula (Hill Notation) C21H31N3O3

  • Molecular Weight 373.49

  •  PubChem Substance ID 329768671

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Properties

Related Categories Asymmetric Synthesis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cycloaddition,
Quality Level   100
form   powder
reaction suitability   reaction type: Asymmetric synthesis
  reagent type: catalyst
reaction type: Photocatalysis
storage temp.   2-8°C
SMILES string   OC1=C(/C=N/[C@@H](C(C)C)C(N2[C@H](C(NCCCC)=O)CCC2)=O)C=CC=C1
InChI   1S/C21H31N3O3/c1-4-5-12-22-20(26)17-10-8-13-24(17)21(27)19(15(2)3)23-14-16-9-6-7-11-18(16)25/h6-7,9,11,14-15,17,19,25H,4-5,8,10,12-13H2,1-3H3,(H,22,26)/b23-14+/t17-,19-/m0/s1
InChI key   DULOQBOELOOGIJ-DYOPXDPWSA-N

Description

Application

Chiral ligand for the asymmetric [2+2] cycloaddition of enones by photoredox catalysis.

Packaging

50 mg in glass bottle

Other Notes

A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Yoon Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Yoon Group – Professor Product Portal
Keywords: Catalysis, Cycloadditions, Ligands, Oxidations

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