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798835 Sigma-Aldrich

[Ru(phd)3](PF6)2

Synonym: Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)

  • CAS Number 184023-77-6

  • Empirical Formula (Hill Notation) C36H18F12N6O6P2Ru

  • Molecular Weight 1021.56

  •  PubChem Substance ID 329768673

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
Quality Level   100
reaction suitability   reagent type: catalyst
SMILES string   F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
InChI   1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
InChI key   LGAOGZFZNIEFHF-UHFFFAOYSA-N

Description

Application

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)3](PF6)2 is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Packaging

100 mg in glass bottle

Legal Information

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

Stahl Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Stahl Group – Professor Product Portal
Keywords: Aerobic, Catalysis, Dehydrogenation, Filtration, Oxidations, Pharmaceutical, Purification

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903426 Ru(p-CF3-bpy)3 (BF4)2, ≥95%

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