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798894 Sigma-Aldrich

SnAP DA Reagent

Synonym: tert-Butyl (3-aminopropyl)((tributylstannyl)methyl)carbamate

  • CAS Number 1577233-73-8

  • Empirical Formula (Hill Notation) C21H46N2O2Sn

  • Molecular Weight 477.31

  •  PubChem Substance ID 329768679

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Properties

Related Categories Chemical Synthesis, Organometallic Reagents, SnAP Reagents More...
InChI Key   IXXRAKGOXZKYBH-UHFFFAOYSA-N
form   liquid
storage temp.   −20°C

Description

Application

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-Heterocycles through SnAP Reagents require mild reaction conditions and aldehydes bearing aryl, heteroaryl, aliphatic, halogenated and glyoxylates are well tolerated. This product was introduced in collaboration with the Jeffrey Bode Research Group.

Packaging

1, 5 g in glass bottle

Other Notes

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles

Safety & Documentation

Safety Information

RIDADR 
UN 2788 6.1 / PGIII

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Jeffrey Bode Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Jeffrey Bode Group – Professor Product Portal
Keywords: Annulations, Asymmetric synthesis, Catalysis, Cross couplings, transformation

SnAP Reagents

Saturated N-heterocyclic building blocks are of growing importance but their installation has been challenging due to poor commercial availability and the often long, laborious synthetic routes neede...
Keywords: Building blocks, Chromatography, Column chromatography, Purification

Peer-Reviewed Papers
15

References

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